Product ID:P4682, PHENOL SATURATED WITH 0.1 M (SUPDAT)
MSDS Date:07/01/1999
FSC:6505
NIIN:00N092651
Status Code:A
MSDS Number: CJVLX

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

(PHENOL SATURATED WITH 0.1 M CITRATE BUFFER

CAS: 108-95-2

RTECS: SJ3325000

OSHA PEL 19 MG/M3;5 PPM

ACGIH TLV: 19 MG/M3;5 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50: (ORAL,RAT) 317 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. MATL IS EXTREMELY DESTRUCTIVE TO TISS OF
MUCOUS MEMBRANES & UPPER RESP TRACT, EYES & SKIN. INHALATION MAY
RESULT IN SPASM, INFLAMMATION & EDEMA OF LARYNX & BRONCHI,
CHEMICAL PNEUMONITIS & PULMONARY EDEMA. SYMPTOMS OF EXPOSURE MAY
INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS,
SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMIT ING. EXPOSURE CAN
CAUSE: DERMATITIS. MAY CAUSE NERV SYS DISTURBS. INGESTION CAN CAUSE
CIRCULATORY COLLAPSE, TACHYPNEA, PARALYSIS, CONVULSIONS, COMA,
NECROSIS OF MOUTH & GI TRACT, (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: JAUNDICE, DEATH FROM RESPIRATORY
FAILURE, SOMETIMES FROM CARDIAC ARREST. READILY ABSORBED THROUGH
SKIN. CHRONIC EFFECTS. TARGET ORGAN(S): CENTRAL NERVOUS SYSTEM,
KIDNEYS, LIVER, PANCREAS, S PLEEN. TO THE BEST OF MANUFACTURER'S
KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES
HAVE NOT BEEN THOROUGHLY INVESTIGATED.

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
COTAMINATED CLOTHING AND SHOES. ASSURE ADEQUATE FLUSHING OF THE
EYES BY SEPARATI NG THE EYELIDS W/FINGERS. IF INHALED, REMOVE TO
FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH
WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN
IMMEDIATELY. WASH CONTAMINATED CLOTHING BEFORE REUSE.

Flash Point:=79.4C, 175.F
Extinguishing Media:WATER SPRAY. CABON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
EYES. COMBUSTIBLE.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPRVD
SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER
GLOVES. COVER W/DRY LIME OR SODA ASH, PICK UP, KEEP IN CLOSED
CONTAINER AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND WASH
SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

Handling and Storage Precautions:DO NOT BREATHE VAP. DO NOT GET IN
EYES, ON SKIN, ON CLTHG. AVOID PRLNGD/RPTD EXPOS. KEEP TIGHTLY
CLSD. KEEP AWAY FROM HEAT & OPEN FLAME. LABEL PRECAUTIONARY
STATEMENTS: TOXIC. TOXIC BY INHAL, IN CONT W/SKIN & IF SWALLOWED.
CAUSES BURNS. VESICANT. READILY ABSORBED THROUGH SKIN. COMBUSTIBLE.
Other Precautions:TARGET ORGAN(S): CNS, KIDNEYS. UNPLEASANT ODOR. IN
CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW
LBL WHERE POSS). IN CASE OF CONT W/EYES, RINSE IMMED W/PLENTY OF
WATER & SEEK MED AD VICE. TAKE OFF IMMED ALL CONTAMD CLTHG. WEAR
SUITABLE PROT CLTHG, GLOVES & EYE/FACE PROTECTION.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR WITH
FACESHIELD (8-INCH MINIMUM).
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: CITRATE BUFFER MOLECULAR BIOLOGY REAGENT. TOX
INFO: SCU-RAT LD50:460 MG/KG. TOIZAG 10,1,1963. ORL-MUS LD50:270
MG/KG. GISAAA 38(8),,6,1973. IHL-MUS LC50:177 MG/M3. GISAAA 41(6)
,103,1976. IPR-MUS LD50:180 MG/KG. PHMCAA 10,172,1968. SCU-MUS
LD50:180 MG/KG. INHEAO 5,143,1967. (OTHER INFO)

Spec Gravity:1.05
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS. MAY DISCOLOR ON
EXPOSURE TO LIGHT.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.

Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
RCRA WASTE NUMBER: U188.

Toxicological Information:RTECS #: SJ3325000. PHENOL. IRRIT DATA:
SKN-RBT 500 MG/24H SEV. BIOFX* 27-4/1973. SKN-RBT 535 MG OPEN SEV.
UCDS** 1/6/1966. SKN-RBT 100 MG MLD. KSGZA3 33,518,1980. EYE-RBT 5
MG SEV. UCDS** 1/6/1966. E YE-RBT 5 MG/30S RINSE MLD. TXCYAC
23,281,1982. TOX DATA: ORL-INF LDLO:10 MG/KG. 34ZIAG -,463,1969.
ORL-HMN LDLO:14 GM/KG. 34ZIAG -,463,1969. ORL-HMN LDLO:140 MG/KG.
29ZWAE -,329,1968. ORL-RAT LD50:317 MG/KG. PSEBAA 32,592,1935.
IHL-RAT LC50:316 MG/M3. GISAAA 41(6),103,1976. SKN-RAT LD50:669
MG/KG. BJIMAG 27,155,1970. IPR-RAT LD50:127 MG/KG. FCTOD7
22,665,1984. (SUPDAT)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE. --OTHER INFO: EFTS ON EMBRYO/FETUS
(FETOTOXICITY). ONLY SELECTED REGISTRY OF TOXIC EFTS OF CHEM
SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN
RTECS FOR COMPLET E INFO.--FED REGULATORY INFO: EPA FIFRA 1988
PESTICIDE SUBJECT TO REGISTRATION/RE-REGISTRATION FEREAC
54,7740,1989. MSHA STD-AIR:TWA 5 PPM (19 MG/M3) (SKIN). CFRGBR
29,1910.1000,1994. OSHA PEL (GEN IN DU):8H TWA 5 PPM (19 MG/M3)
(SKIN). CFRGBR 29,1910.1000,1994. OSHA PEL (CONSTRUC):8H TWA 5 PPM
(19 MG/M3) (SKIN). CFRGBR 29,1926.55,1994. OSHA PEL (SHIPYARD):8H
(TRANSPORT INFO)

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION. --ECOLOGICAL INFO: TWA 5 PPM (19 MG/M3) (SKIN) CFRGBR
29,1915.1000,1993. OSHA PEL (FED CONT):8H TWA 5 PPM (19 MG/M3)
(SKIN) CFRGBR 41,50- 204.50,1994. OEL-ARAB REPUBLIC OF EGYPT:TWA 5
PPM (19 MG/M3);SKIN JAN 1993. OEL-AUSTRALIA:TWA 5 PPM (19
MG/M3);SKIN JAN 1993. OEL-BELGIUM:TWA 5 PPM (19 MG/M3);SKIN JAN
1993. OEL-DENMARK:TWA 5 PPM (19 MG/M3);SKIN JAN 1993.
OEL-FINLAND:TWA 5 PPM (19 MG/M3);STEL 10 PPM (38 MG/M3);SKIN JAN
1993. OEL-FRANCE:TWA 5 PPM (19 MG/M3);SKIN JAN 1993.
OEL-GERMANY:TWA 5 PPM (19 MG/M3);SKIN JAN 1993. (SARA TITLE III)

SARA Title III Information:U.S. INFORMATION. THIS PRODUCT IS SUBJECT TO
SARA SECTION 313 REPORTING REQUIREMENTS. --TRANSPORT INFO:
OEL-HUNGARY:TWA 4 MG/M3;STEL 8 MG/M3;SKIN JAN 1993. OEL-JAPAN:TWA 5
PPM (19 MG/M3);SKIN JAN 1993 . OEL-THE NETHERLANDS:TWA 5 PPM (19
MG/M3);SKIN JAN 1993. OEL-THE PHILIPPINES:TWA 5 PPM (10 MG/M3);SKIN
JAN 1993. OEL-POLAND:TWA 10 PPM JAN 1993. OEL-RUSSIA:TWA 5 PPM;STEL
0.3 MG/M3;SKIN JAN 1993. OEL -SWEDEN:TWA 1 PPM (4 MG/3);STEL 2 PPM
(8 MG/M3);SKIN JAN 1993. OEL-SWITZERLAND:TWA 5 PPM (19 MG/M3);STEL
10 PPM (38 MG/M3);SKIN JAN 1993. OEL-THAILAND:TWA 5 PPM (19 MG/M3)
JAN 1993. (STATE REGULATORY INFO)
Federal Regulatory Information:EUROPEAN INFO. EC INDEX NO:
604-001-00-2. TOXIC. R 24/25. TOXIC IN CONT W/SKIN & IF SWALLOWED.
4 34. CAUSES BURNS. S 28. AFTER CONT W/SKIN, WASH IMMED W/PLENTY OF
WATER. S 45. IN CASE OF ACCIDENT/IF Y OU FEEL UNWELL, SEEK MED
ADVICE IMMED (SHOW LBL WHERE POSS). REVIEWS, STDS, & REGS. OEL=MAK.
ACGIH TLV-NOT CLASSIFIABLE AS HUMAN CARCIN DTLVS* TLV/BEI,1997.
ACGIH TLV-TWA 19 MG/M3 (5 PPM) (SKIN) DTLVS * TLV/BEI,1997. IARC
CANCER REVIEW:ANIMAL INADEQ EVID IMEMDT 47,263,1989. IARC CANCER
REVIEW: HUMAN INADEQ EVID IMEMDT 47,263,1989. IARC CANCER
REVIEW:GROUP 3. IMEMDT 47,263,1989. (TRANSPORT INFO)
State Regulatory Information:N/P. --SARA TITLE III: OEL-TURKEY:TWA 5
PPM (19 MG/M3);SKIN JAN 1993. OEL-UNITED KINGDOM:TWA 5 PPM (19
MG/M3);STEL 10 PPM;SKIN JAN 1993. OEL IN BULGARIA, COLOMBIA, JORDN,
KOREA CHECK ACGIH TLV. OEL IN NEW ZEALAND, SIGAPORE, VIETNAM CHECK
ACGIH TLV. NIOSH REL TO PHENOL-AIR:10H TWA 5 PPM (SK);CL 15.6
PPM/15M (SK). NIOSH* DHHS #92-100,1992. NOHS 1974: HZD 55460;NIS
185; TNF 23275; NOS 127; TNE 296662 . NOES 1983: HZD 55460; NIS
229; TNF 31983; NOS 155; TNE 584372; TFE 120977. ATSDR TOX PROFIE
(NTIS* * PB/90/181249/AS). EPA GENETOX PROGRAM 1988, NEG: N
CRASSA-REVERSION. FOR MORE INFO CONT NEHC .